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  您現在的位置:上海富柏化工有限公司 > 產品展示 > 產品展示 > 有機棕化
有機棕化

一、產品簡介
I Product Introduction

有機棕化是為了提供更高的多層線路板之內層結合力而設計。它具有良好粗化表面的有機金屬轉化層,與環氧樹脂具有良好的附著力;同時也適用于各種需要提高銅面結合力的不同制程。有機棕化制程是在低溫下操作,適用于垂直或水平的操作模式,且能以添加補充,溢流方式完成自動藥液控制。 具有槽液壽命長、節省人工、藥水等特點,及廢水處理容易;高銅含量,減少換槽頻率;有效解決粉紅圈問題,產品品質高。
Organic oxidation is designed to provide the cohesion in multi-layer circuit. It has organic metal transfer layer with good roughened surface, and has good attachment to epoxy resin; and meanwhile, it is applicable to various processes requiring improving copper surface cohesion. The organic oxidation process is operated under low temperature, and is applicable to vertical or horizontal operating mode, and can finish automatic solution control through adding and over flow. It has such strong points as long use life of solution, saving labor and solution, easy treatment of waste water, high copper content, and reducing frequency of replacing bath, and can effectively solve the problem of pink ring and improve quality of product.

二、產品優勢
II Product Advantages

1、配槽及藥液維護簡單;
1. Easy makeup and maintenance of solution;
2、操作安全性高、低溫操作即可(<40℃);
2. Operation has high safety and low temperature for operation is enough (<40℃);
3、優良的信賴性測試;
3. Good testing of reliability;
4、無粉紅圈;
4. No pink ring;
5、處理能力大、操作成本低;
5. Large processing ability, and low operating cost;
6、可適用水平或垂直制程。
6. Be applicable to horizontal or vertical process;

三、配槽方法 III Makeup Method
(A) 除油槽
(A) Deoiling bath

1L槽液
1L solution
主要作用
Main Function
體積(ml)
Volume
純水
Pure water
溶劑
Solvent
900ml
除油劑
Deoiling agent
除油
Deoiling
100ml
(B)預浸槽
(B) Pre-dipping bath
1L槽液
1L solution
主要作用
Main Function
體積(ml)
Volume
純水
Pure water
溶劑
Solvent
950ml
預浸液
Ore-dipping solution
活化
Activation
50ml
(C) 有機棕化槽
(C)Organic oxidation bath
1L槽液
1L solution
主要作用
Main Function
體積(ml)
Volume
純水
Pure water
溶劑
Solvent
714ml
硫酸(50%)
Sulfuric acid
提供酸環境
Provide acid environment
36ml
ZH-555A 成膜劑
Film forming agent
200ml
ZH-555B 氧化劑
Oxidant
50ml

四、分析方法
IV Analysis Method
(一)除油劑

1、 取10 ml工作液,置入250ml錐形瓶中;
1. Take 10ml working solution and place it in a 250ml conical flask;
2、加入50 ml純水及5滴甲基橙指示劑;
2. Add 50ml pure water and 5 drops of methyl orange indicator;
3、 用0.1 N NaOH滴定,滴至黃色為終點。
3. Use 0.1 N NaOH for titration till the solution becomes yellow;
計算:濃度(%) = V0.1 N NaOH ( ml ) ×0.3
Calculation: concentration (%) = V0.1 N NaOH ( ml ) ×0.3
添加:欲提高除油槽1%時,需加槽體積的1%之除油劑。
Add: to improve 1% deoiling bath, add deoiling agent with amount be 1% of flot volume;

(二)預浸劑
(II) Pre-dipping Agent

一般在棕化槽達到換槽的同時,預浸槽應同時換槽。
When the oxidation bath shall be replaced, replace the pre-dipping bath at the same time;

(三)有機棕化劑 ZH-555A濃度
(II) Organic Oxidation Agent ZH-555A Concentration

1、量取1ML槽液于錐形瓶中,加入100mlDI水;
1. Measure 1ml solution in conical flask and add 100ml DI water;
2、加入3-5滴甲基橙指示劑,用0.1N 氫氧化鈉標準溶液滴定至溶液呈黃色。
2. Add 3-5 drops of methyl orange indicator, and use 0.1N standard sodium hydroxide solution for titration till the solution becomes yellow;
計算:ZH-555A濃度g/L = 氫氧化鈉標準溶液(ML)×4.9
Calculation: :ZH-555A Concentratioin g/L = tandard sodium hydroxide solution (ml) ×4.9
添加:欲提高10g/LA濃度,加槽體積2.5%的SBZH-A, 維護A濃度100g/L的最佳濃度
Add: to improve concentration A by 10g/L, add SBZH-A with amount be 2.5% of bath volume, and maintain the concentration A be 100g/L

(四)有機棕化劑 ZH-555B 濃度
(IV) Organic Oxidation Agent ZH-555B Concentration

1、量取1ML槽液于250ML錐形瓶中;
1. Measure 1ml solution in a 250ml conical flask;
2、加入100MLDI水;
2. Add 100ml DI water;
3、加入20ML 20%硫酸;
3. Add 20ml 20% sulfuric acid;
4、用0.1N 高錳酸鉀標準溶液滴定至溶液呈透明為終點。
4. Use 0.1N standard potassium permanganate solution for titration till the solution becomes transparent;
計算:ZH-555B 濃度(g/L)=高錳酸鉀標準液用量(ML)×1.701
Calculation: ZH-555B concentration (g/L) = usage of standard potassium permanganate solution (ml) ×1.701
添加:欲提高1g/L B濃度, 加槽體積0.35%之SBZH-B,維護B濃度15g/L的最佳濃度
Add: to improve concentration B by 10g/L, add SBZH-B with amount be 0.35% of bath volume, and maintain the concentration B be 15g/L

(五)有機棕化劑:銅離子
(V) Organic Oxidation Agent: Copper ion

1、量取1ML槽液于錐形瓶中;
1. Measure 1ml solution in a conical flask;
2、加入50ML熱DI水(80-100℃);
2. Add 50ml hot DI water (80-100℃);
3、加入4ML的濃氨水使溶液顏色呈藍、綠色;
3. Add 4ml concentred ammonia to change the solution color into blue-green;
4、加入3滴PAN指示劑;
4. Add 3 drops of PAN indicator;
5、以0.1N EDTA標準溶液滴定顏色由深棕色至綠色終點。
5. Use 0.1N EDTA standard solution for titration till the solution changes from dark brown to green;
計算:銅離子(g/L)= V(EDTA滴定用量)× 6.354
Calculation: copper ion (g/L) = V(usage of EDTA)× 6.354

五、信賴度測試
V Reliability Test
檢測項目
Testing Item
處理流程
Processing Flow
判斷標準
Judge Standard
微蝕深度
Micro-etching Concentration
水平棕化線
Horizontal oxidation line
40-100
抗粉紅圈
Anti-pink ring
  Non
剝離強度
Stripping strength
Lamination >4.0 1b/in(1OZ copper foil)
漂錫測試
Solder float test
Lamination 288°10Set>6Cycle無白點 無分層
288°10Set>6Cycle, no white pint, no layer
浸錫測試
Solder dipping test
Lamination 288°10Set>6Cycle無白點 無分層
288°10Set>6Cycle, no white pint, no layer
外觀檢查
Appearance inpsection
  均勻的棕黑色
Average brown-black

(一)微蝕深度
(I) Micro-etching depth

目的:以重量差法測試內層銅面的咬蝕深度
Target: use weight-difference method to test the fretting corrosion depth of inner copper surface
步驟:
Steps:
1、取雙面覆銅板(WXL);
1. Take double-side copper-coated board (WXL);
2、以砂紙處理表面的鈍化層,并以清水清洗干凈;
2. Use sand paper to process the passivation layer of surface and clean with clean water;
3、以120度,20分鐘烘干,并稱重 W1;
3. Dry under 120℃ for 20 minutes and weight it W1;
4、走棕化全流程;
4. Go through oxidation flow;
5、以120度,20分鐘烘干,并稱重 W2。
5. Dry under 120℃ for 20 minutes and weight it W2;
計算方法: 微蝕深度=(W1-W2)*106/(W*L*2*2.54*8.94)
Calculation method: micro-etching depth = W1-W2)*106/(W*L*2*2.54*8.94)
(二)抗粉紅圈測試
(II) Anti-pink ring test
目的:測試棕化膜層耐酸攻擊的品質,以確保能有效防止粉紅圈的發生
Target:test the acid-resistance of oxidation film to ensure it can effectively avoid oink ring;
步驟:
Steps:
1、取壓合后的板子鉆各種不同的孔徑;
1. Take compressed board and drill holes with different diameter;
2、走正常的流程到蝕刻結束,蝕刻掉表面的銅;
2. Go through normal flow till the end of etching and removing the copper on surface;
3、目視觀察各孔周圍是否有粉紅圈發生。
3. Visually observe if there is pink ring surrounding the holes;
(三)抗剝離強度測試
(III) Anti-stropping strength test
目的:測試棕化層經壓合后與膠片間的結合力
Target: test the cohesion between pressed oxidation layer and film
步驟:
Steps:
1、取1OZ銅箔固定于基板表面,走棕化流程并干燥之;
1. Take 10Z copper foil and fix it on surface of baseboard, go through oxidation flow and dry it;
2、將棕化后的銅箔貼于無銅芯片上壓合,壓合的排列由上到下為:
2. Press oxided copper foil on copperless chip, pressing order from up to down is:
棕化銅箔/7628+1080/芯片/1080+7628/棕化銅箔;
Oxided copper foil /7628+1080/ chip /1080+7628/ oxided copper foil;
3、將壓合后的銅箔經蝕刻做出標準的測試圖形;
3. Etch the pressed copper foil and make standard testing figure;
4、用拉力機測試銅箔與膠片間的拉力值。
4. Use the tensile machine to test the tensile value between copper foil and film;

六、槽液壽命
VI Use Life of Solution

當槽液銅離子達到25g/L時,可將50%液排出,重新配50%體積之新液或補充添加的方式維持槽液銅離子在15g/L左右之穩定狀態。
When the copper ion in solution reaches 25g/L, drain out 50% solution, re-makeup new solution with a volume of 50% or maintain copper ion at about 15g/L in solution in the way of supplemental adding.

七、產品性質
VII Product Nature

品名
Product name
除油劑
Deoiling agent
預浸液
Pre-dipping
ZH-555A ZH-555B
外觀
Appearance
無色至淡黃色透明液體
Colorless to light yellow transparent liquid
無色至淡黃色透明液體
Colorless to light yellow transparent liquid
淡黃色液體
Light yellow liquid
無色透明液體
Colorless transparent liquid
氣味
Odor

No

No
略有
A little
略有
A little
燃點
Ignition point
不可燃
Non- combustible
不可燃
Non- combustible
不可燃
Non- combustible
不可燃
Non- combustible
比重
Specific gravity
1.10-1.20 1.05-1.15 1.21-1.25 1.05-1.15
儲存溫度
Store temperature
室溫
Room temperature
室溫
Room temperature
3℃-35℃ 3℃-35℃
八、安全防護
VIII Safety Protection

1、使用本產品請先閱讀本產品之物質安全資料,操作時請佩帶防護設備;
1. Before using the product, please read the Material Safety Data of the product and wear protective device during operation;
2、若有不慎觸及身體時請以大量清水沖洗15分鐘,本產品儲存于干爽環境下;
2. In case of contact with body, flush with plenty of clean water for 15 minutes; store the product in dry and cool place;
3、ZH-555B含有雙氧水,會使眼睛、皮膚灼傷需特別注意;
3. ZH-555B contains H2O2 and may hurt eye and skin, please be careful when using it;
4、藥水開封后請在一月內使用完。
4. Please use up the solution within one month after unsealing;


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